Creating Stereocenters within Acyclic Systems by C-C Bond Cleavage of Cyclopropanes.
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DOI: 10.1021/acs.chemrev.0c00167
Abstract: Recent developments in the stereoselective synthesis of polysubstituted cyclopropanes nowadays allow chemists to easily access these strained rings with high diastereo- and enantiomeric ratios. In turn, this development has created a paradigm shift for the… read more here.
Keywords: cleavage; acyclic systems; bond cleavage; stereocenters within ... See more keywords
Stereoselective Preparation of Distant Stereocenters (1,5) within Acyclic Molecules
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DOI: 10.1021/acscatal.0c01762
Abstract: The development of a modular and diastereodivergent approach to acyclic products bearing two distant stere-ocenters in a 1,5 relationship is reported. Remarkably, it was accomplished in just three ... read more here.
Keywords: stereoselective preparation; acyclic molecules; preparation distant; within acyclic ... See more keywords