Correlating Structural Features and 207Pb NMR Parameters with the Stereochemical Activity of PbII Lone Pairs in Birefringent Pb[2,6-bis(benzimidazol-2-yl)pyridine] Complexes
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DOI: 10.1002/ejic.201601235
Abstract: A series of PbII materials containing the highly anisotropic tridentate ligand 2,6-bis(benzimidazol-2-yl)pyridine (bbp) and [Au(CN)2]–, Hg(CN)2 or halide bridging units, [Pb(bbp)Br2]·2H2O, Pb(bbp)I2, [Pb(bbp)I]2(µ-I)[Au(CN)2], [Pb(bbp)Br]2(µ-Br)[Au(CN)2], [Pb(bbp)Br2][Hg(CN)2], Pb(bbp)Cl[Au(CN)2]·0.25H2O and Pb(H2O)(bbp)2[Au(CN)2]2, have been prepared, structurally characterised and investigated… read more here.
Keywords: lone; bis benzimidazol; bbp; stereochemical activity ... See more keywords