Asymmetric Synthesis and Stereochemical Assignment of 12C/13C Isotopomers.
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DOI: 10.1021/jacs.9b07181
Abstract: A synthesis of chiral hydrocarbons having C1 axis and C3 symmetry, which owe their chirality due to asymmetrical distribution of 12C/13C isotopes, is reported. Their absolute configurations assigned using the vibrational circular dichroism (VCD) technique… read more here.
Keywords: 12c 13c; synthesis stereochemical; stereochemical assignment; asymmetric synthesis ... See more keywords