Stereochemical switch driven by crystallization: Interplay between stoichiometry and configuration of the products.
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DOI: 10.1002/chir.23451
Abstract: An intriguing example of a crystallization-induced stereochemical switch in the configuration of aza-Michael reaction products is described. Depending on both the stereochemical purity and stoichiometric ratio of the chiral amine used, the reaction delivers crystalline… read more here.
Keywords: switch driven; stereochemical switch; crystallization; configuration ... See more keywords