Defining Stereochemistry in the Polymerization of Lactide by Aluminum Catalysts: Insights into the Dual-Stereocontrol Mechanism.
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DOI: 10.1021/jacs.2c09073
Abstract: Aspects of the proposed pathway combining chain-end and enantiomorphic site control for the stereospecific polymerization of lactide (LA) were investigated through studies of aluminum complexes supported by enantiopure and racemic bipyrrolidine-based salan ligands, Lig1AlOBn and… read more here.
Keywords: polymerization lactide; defining stereochemistry; stereochemistry; stereocontrol ... See more keywords