Stereochemistry, Stereodynamics, and Redox and Complexation Behaviors of 2,2'-Diaryl-1,1'-Biazulenes.
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DOI: 10.1002/cplu.201900262
Abstract: 2,2'-Diaryl-1,1'-biazulenes were synthesized and electronic communication between the azulene subunits was suggested based on redox measurements. The linkage of azulene at the 1-position also appeared to increase the HOMO levels. In addition, cyclic voltammetry measurements… read more here.
Keywords: diaryl biazulenes; stereochemistry stereodynamics; stereodynamics redox; redox complexation ... See more keywords