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Published in 2019 at "ACS Omega"
DOI: 10.1021/acsomega.9b00380
Abstract: The crystallization behavior of a series of synthesized polylactide (PLA)/poly(δ-valerolactone) (PVL) supramolecular copolymers with 2-ureido-4[1H]-pyrimidinone (UPy) groups is investigated by differential scanning calorimetry and X-ray diffraction. The stereocomplexation of PLA-based supramolecular polymers (SMPs) is strongly…
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Keywords:
pla;
stereocomplexation;
poly valerolactone;
crystallization ... See more keywords
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Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c02981
Abstract: Stereocomplexation is a useful strategy for the enhancement of polymer properties by the co-crystallization of polymer strands with opposed chirality. Yet, with the exception of PLA, stereocomplexes of biodegradable polyesters are relatively underexplored and the…
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Keywords:
semicrystalline polymers;
stereocenter inversion;
single stereocenter;
polymers single ... See more keywords
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Published in 2017 at "Polymers"
DOI: 10.3390/polym10010008
Abstract: The crystallization and morphology of PLA-mb-PBS copolymers and their corresponding stereocomplexes were studied. The effect of flexible blocks (i.e., polybutylene succinate, PBS) on the crystallization of the copolymers and stereocomplex formation were investigated using polarized…
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Keywords:
pbs;
pla;
stereocomplexation;
formation ... See more keywords