Solvent Clathrate Driven Dynamic Stereomutation of a Supramolecular Polymer with Molecular Pockets.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b07639
Abstract: Control over the helical organization of synthetic supramolecular systems is intensively pursued to manifest chirality in a wide range of applications ranging from electron spin filters to artificial enzymes. Typically, switching the helicity of supramolecular… read more here.
Keywords: molecular pockets; stereomutation; solvent molecules; clathrate driven ... See more keywords
Stereomutation in Tetracoordinate Centers via Stabilization of Planar Tetracoordinated Systems
Sign Up to like & getrecommendations! Published in 2021 at "Atoms"
DOI: 10.3390/atoms9040079
Abstract: The quest for stabilizing planar forms of tetracoordinate carbon started five decades ago and intends to achieve interconversion between [R]- and [S]-stereoisomers without breaking covalent bonds. Several strategies are successful in making the planar tetracoordinate… read more here.
Keywords: planar; energy; stereomutation; form ... See more keywords