Cu-Catalyzed Stereoselective Borylation of gem-Difluoroalkenes with B2pin2.
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DOI: 10.1021/acs.orglett.7b01430
Abstract: A novel and efficient method for the synthesis of (Z)-fluorinated alkenylboronic acid pinacol esters via Cu-catalyzed stereoselective borylation of gem-difluoroalkenes using bis(pinacolato)diboron (B2pin2) as the boron source with the assistance of NaOtBu and Xantphos at… read more here.
Keywords: gem difluoroalkenes; borylation gem; catalyzed stereoselective; stereoselective borylation ... See more keywords