Silylium-Catalyzed Regio- and Stereoselective Carbosilylation of Ynamides with Allylic Trimethylsilanes
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DOI: 10.1021/acs.orglett.3c00221
Abstract: The regio- and stereoselective carbosilylation of tosylynamides with allylic trimethylsilanes takes place under mild conditions in the presence of catalytic TMSNTf2 or HNTf2 to give (Z)-α-allyl-β-trimethylsilylenamides with good yields. Theoretical calculations show the activation of… read more here.
Keywords: catalyzed regio; stereoselective carbosilylation; regio stereoselective; allylic trimethylsilanes ... See more keywords