Stereoselective Catalytic Synthesis of Alkynylated Phosphaethenes Leading to Activation‐Free Gold Catalysis
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DOI: 10.1002/ejoc.201701259
Abstract: The π-accepting property of alkene-like phosphaethenes (-P=C read more here.
Keywords: alkynylated phosphaethenes; synthesis alkynylated; gold; activation free ... See more keywords
Stereoselective and Catalytic Synthesis of anti-β-Alkoxy-α-azido Carboxylic Derivatives.
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DOI: 10.1021/acs.orglett.7b03255
Abstract: Direct addition of a chiral N-azidoacetyl thiazolidinethione to a variety of dialkyl acetals catalyzed by a commercially available and structurally simple nickel(II) complex gives access in good yields and a highly stereocontrolled manner to anti-β-alkoxy-α-azido… read more here.
Keywords: alkoxy azido; azido carboxylic; anti alkoxy; catalytic synthesis ... See more keywords
Highly Regio- and Stereoselective Catalytic Synthesis of Conjugated Dienes and Polyenes.
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DOI: 10.1021/jacs.8b05421
Abstract: Conjugated dienes and polyenes are typically synthesized by sequential introduction of C═C bonds. Here, we report a practical and scalable, catalytic dienylation that is highly regio- and stereoselective for both C═C bonds. The reaction is… read more here.
Keywords: conjugated dienes; dienes polyenes; stereoselective catalytic; regio stereoselective ... See more keywords