Regioselective and stereoselective cleavages of P–S/C–S bonds by lithium and the formation of P-stereogenic functional phosphine derivatives
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DOI: 10.1039/d0qo00891e
Abstract: Various menthyl-containing phosphinothioates were prepared. Using these compounds, an unusual phosphorus-promoted cleavage of the C–S bond with lithium-naphthalene was examined. The C–S/P–S cleavages could be controlled by the amount of naphthalene and temperature applied. Also,… read more here.
Keywords: regioselective stereoselective; lithium formation; stereoselective cleavages; bonds lithium ... See more keywords