A stereoselective construction of a cis-1,2-oxazadecaline skeleton using a substrate-controlled intramolecular oxy-Michael addition of tyrosine-derived hydroxylamines
Sign Up to like & getrecommendations! Published in 2020 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2019.151412
Abstract: Abstract A method for the stereoselective construction of cis-1,2-oxazadecaline skeletons via a substrate-controlled intramolecular oxy-Michael addition of readily available tyrosine-derived hydroxylamines has been developed. The approach features an eight-step synthesis of the optically active cis-1,2-oxazadecaline… read more here.
Keywords: cis; substrate controlled; controlled intramolecular; cis oxazadecaline ... See more keywords
Stereoselective Construction of Chiral Linear [3]Catenanes and [2]Catenanes.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c12027
Abstract: We have successfully constructed a chiral linear [3]catenane stereoselectively by coordination-driven self-assembly using a ditopic monodentate ligand containing l-valine residues with a binuclear half-sandwich organometallic rhodium(III) unit. Furthermore, by increasing the steric hindrance of the… read more here.
Keywords: stereoselective construction; catenane; chiral linear; catenanes catenanes ... See more keywords