Stereoselective gem-C,B-Glycosylation via 1,2-Boronate Migration.
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DOI: 10.1021/jacs.1c11842
Abstract: A novel protocol is established for the long-standing challenge of stereoselective geminal bisglycosylations of saccharides. The merger of PPh3 as a traceless glycosidic leaving group and 1,2-boronate migration enables the simultaneous introduction of C-C and… read more here.
Keywords: boronate migration; gem glycosylation; stereoselective gem; boronate ... See more keywords