Copper(I)-catalyzed stereoselective hydrogenation of 1,3-diynes and enynes
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DOI: 10.1016/j.tet.2017.05.029
Abstract: A stereoselective hydrogenation of 1,3-diynes with an air-stable copper(I)/N-heterocyclic carbene complex, [IPrCuOH], has been developed. The corresponding products, 1,3-dienes, are obtained in a stereoselective manner depending on their substitution pattern: Diaryl-diynes yield E,E-1,3-dienes, whereas dialkyl-diynes… read more here.
Keywords: stereoselective hydrogenation; hydrogenation; catalyzed stereoselective; hydrogenation diynes ... See more keywords
Reducing Challenges in Organic Synthesis with Stereoselective Hydrogenation and Tandem Catalysis.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c00750
Abstract: Tandem catalysis enables the rapid construction of complex architectures from simple building blocks. This Perspective shares our interest in combining stereoselective hydrogenation with transformations such as isomerization, oxidation, and epimerization to solve diverse challenges. We… read more here.
Keywords: stereoselective hydrogenation; reducing challenges; hydrogenation; tandem catalysis ... See more keywords