Regio- and Stereoselective Organocatalyzed Relay Glycosylations To Synthesize 2-Amino-2-deoxy-1,3-dithioglycosides.
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DOI: 10.1021/acs.orglett.3c00859
Abstract: Herein, we describe a novel methodology for the regio- and stereoselective convergent synthesis of 2-amino-2-deoxy-dithioglycosides via one-pot relay glycosylation of 3-O-acetyl-2-nitroglucal donors. This unique organo-catalysis relay glycosylation features excellent site- and stereoselectivity, good to excellent… read more here.
Keywords: stereoselective organocatalyzed; deoxy dithioglycosides; organocatalyzed relay; amino deoxy ... See more keywords