Resolution of (R,S)-1-(4-methoxyphenyl)ethanol by lipase-catalyzed stereoselective transesterification and the process optimization.
Sign Up to like & getrecommendations! Published in 2021 at "Chirality"
DOI: 10.1002/chir.23402
Abstract: An efficient lipase-catalyzed stereoselective transesterification reaction system was established for resolution of 1-(4-methoxyphenyl)ethanol (MOPE) enantiomers. A series of lipases were tested and compared. The immobilized lipase Novozym 40086 is selected as the best choice. The… read more here.
Keywords: lipase; methoxyphenyl ethanol; stereoselective transesterification; catalyzed stereoselective ... See more keywords
Stereoselective Transesterification of P‐Chirogenic Hydroxybinaphthyl Phosphinates
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DOI: 10.1002/open.202100294
Abstract: Abstract The substitution reaction of phosphinates with a binaphthyloxy group at the phosphorus atom with lithium alkoxides proceeded with good to high efficiencies to give P‐chirogenic phosphinates with a high enantiomeric ratio. As alcohols, primary,… read more here.
Keywords: chirogenic hydroxybinaphthyl; reaction; substitution reaction; transesterification chirogenic ... See more keywords