Promotion Mechanism of H2O for Stereoselectivity in Pd(II)-catalyzed C―H Arylation of Diarylphosphinamides with Arylboronic Acids
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DOI: 10.1007/s40242-019-9013-9
Abstract: On the basis of a series of control experiments and nuclear magnetic resonance analyses, it is discovered that Boc-protected amino acid ligand coordinated to Pd center is partly replaced by N,N-dimethylformamide, and H2O can inhibit… read more here.
Keywords: mechanism; arylation diarylphosphinamides; stereoselectivity catalyzed; arylboronic acids ... See more keywords