Stereoselectivity, Different Oxidation States, and Multiple Spin States in the Cyclopropanation of Olefins Catalyzed by Fe–Porphyrin Complexes
Sign Up to like & getrecommendations! Published in 2018 at "ACS Catalysis"
DOI: 10.1021/acscatal.8b01492
Abstract: The mechanism of the cyclopropanation of alkenes with diazocompounds catalyzed by ClFeIII–porphyrin, [ClFeII–porphyrin]−, and FeII–porphyrin has been investigated by density functional theory calculations. The obtained results indicate that the only viable catalyst is the FeII–porphyrin,… read more here.
Keywords: cyclopropanation; spin states; different oxidation; porphyrin ... See more keywords