Stereospecific [3+2] Cycloaddition of Chiral Arylallenes with C,N-Cyclic Azomethine Imines.
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DOI: 10.1021/acs.orglett.3c00984
Abstract: A novel α,β-regioselective [3+2] cycloaddition reaction of arylallene with C,N-cyclic azomethine imine is reported. The axial-to-central chirality transfer phenomenon has been disclosed with chiral allenes in the reaction. The wide substrate scope, including different functional… read more here.
Keywords: cycloaddition chiral; cycloaddition; stereospecific cycloaddition; cyclic azomethine ... See more keywords