Electronic and steric impact of bis-NHC ligands on reactions of Pt3S2 cores in trinuclear complexes bearing bis-NHC ligands with various lengths of alkylene bridges.
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DOI: 10.1039/d1dt02747f
Abstract: Alkylene-bridged bis-N-heterocyclic carbene ligands working as strong σ-donors enhance the reactivity of the Pt3S2 core in a triplatinum complex. Although an Ag(I) ion possibly reacts with the Pt-Pt bond, one of the sulfide ligands coordinates… read more here.
Keywords: impact bis; bis nhc; electronic steric; steric impact ... See more keywords