Articles with "sterically bulky" as a keyword



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Intracellular Protein Photoactivation Using Sterically Bulky Caging

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Published in 2022 at "ChemBioChem"

DOI: 10.1002/cbic.202200476

Abstract: Methods for intracellular protein photoactivation have been studied to elucidate the spatial and temporal roles of proteins of interest. In this study, an intracellular protein photoactivation method was developed using sterically bulky caging. The protein… read more here.

Keywords: using sterically; photoactivation; intracellular protein; protein photoactivation ... See more keywords
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Palladium(II) complexes containing sterically bulky O, N donor ligands: Synthesis, characterization and catalytic activity in the Suzuki-Miyaura and Sonogashira coupling reactions

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Published in 2020 at "Journal of Organometallic Chemistry"

DOI: 10.1016/j.jorganchem.2019.121080

Abstract: Abstract A new class of palladium(II)1-(arylazo)naphtholate complexes of the type [Pd(L1-4)2] containing sterically bulky O, N donor functionalized arylazo ligands has been synthesized. These palladium(II) complexes were characterized by elemental analysis and spectral (FT-IR, UV–Vis,… read more here.

Keywords: containing sterically; palladium complexes; sterically bulky; bulky donor ... See more keywords
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Direct access to highly crystalline mesoporous nano TiO2 using sterically bulky organic acid templates

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Published in 2018 at "Journal of Physics and Chemistry of Solids"

DOI: 10.1016/j.jpcs.2018.01.043

Abstract: Abstract Sterically bulky monocarboxylic acid templates pivalic acid and phenoxyacetic acid are reported for the first time as organic templates in the sol-gel synthesis of TiO2. Mesoporous nanoparticulates of pure anatase phase and of well… read more here.

Keywords: tio2; sterically bulky; acid templates; direct access ... See more keywords
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Sterically Bulky Caging of Transferrin for Photoactivatable Intracellular Delivery.

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Published in 2021 at "Bioconjugate chemistry"

DOI: 10.1021/acs.bioconjchem.1c00159

Abstract: Photoactivatable ligand proteins are potentially useful for light-induced intracellular delivery of therapeutic and diagnostic cargos through receptor-mediated cellular uptake. Here, we report the simple and effective caging of transferrin (Tf), a representative ligand protein with… read more here.

Keywords: sterically bulky; delivery; bulky caging; cellular uptake ... See more keywords
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Iodine(i) complexes incorporating sterically bulky 2-substituted pyridines

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Published in 2022 at "RSC Advances"

DOI: 10.1039/d2ra01390h

Abstract: The silver(i) and iodine(i) complexes of the 2-substituted pyridines 2-(diphenylmethyl)pyridine (1) and 2-(1,1-diphenylethyl)pyridine (2), along with their potential protonated side products, were synthesised to investigate the steric limitations of iodine(i) complex formation. The complexes were… read more here.

Keywords: incorporating sterically; iodine complexes; complexes incorporating; substituted pyridines ... See more keywords
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Role of Sterically Bulky Azobenzenes in the Molecular Assembly of Pyrene Derivatives: Rectangular Sheet-like Structures and Their Emission Characteristics

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Published in 2023 at "International Journal of Molecular Sciences"

DOI: 10.3390/ijms24054504

Abstract: The development of pyrene-based fluorescent assembled systems with desirable emission characteristics by reducing conventional concentration quenching and/or aggregation-induced quenching (ACQ) is highly desirable. In this investigation, we designed a new azobenzene-functionalized pyrene derivative (AzPy) in… read more here.

Keywords: emission characteristics; like structures; concentration; sheet like ... See more keywords