Sterically Induced Ligand Framework Distortion Effects on Catalytic Cyclic Ester Polymerizations.
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DOI: 10.1021/acs.inorgchem.8b00250
Abstract: Aluminum alkoxide complexes supported by salen ligands [salen = N, N'-bis(salicylaldimine)-2-methylpropane-1,2-diamine or N, N'-bis(salicylaldimine)-2,2-dimethylpropane-1,3-diamine] with o-adamantyl substituents have been synthesized and investigated for the polymerization of ε-caprolactone. Geometric analysis of the catalysts used for the… read more here.
Keywords: framework distortion; distortion effects; sterically induced; induced ligand ... See more keywords
Sterically Induced Acceleration of Aryl Halide Activation by Pd(0): A Radical Alternative to 2‑Electron Oxidative Addition
Sign Up to like & getrecommendations! Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.5c04407
Abstract: The first elementary step of Pd(0)-catalyzed cross-coupling involves the activation of an aryl halide by a Pd(0) catalyst, which is widely assumed to proceed in a formal 2-electron process, involving concerted cleavage of the aryl… read more here.
Keywords: sterically induced; aryl halide; electron; activation ... See more keywords