Piano stool complexes of N-heterocyclic carbene ligands bearing a galactose-derived substituent
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.119651
Abstract: Abstract Piano stool complexes of NHC ligands bearing a chiral auxiliary derived from α-ᴅ-galactose, and linked through the C-6 carbon atom, have been synthesized and structurally characterized by single crystal X-ray diffraction. [(η6-C6H3Me3)RuCl2(κC-1,3-MeNC3H2NR)], R = 1,2:3,4-di-O-isopropylidene-6-deoxy-α-D-galactopyran-6-yl, (4)… read more here.
Keywords: piano stool; complexes heterocyclic; ligands bearing; stool complexes ... See more keywords
PM-IRRAS and DFT investigation of the surface orientation of new Ir piano-stool complexes attached to Au(111).
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02730e
Abstract: Surface immobilization of organometallic catalysts is a promising approach to developing new catalytic systems that combine molecular catalysts with heterogenous surfaces to probe surface mechanisms. The orientation of the catalyst relative to the surface is… read more here.
Keywords: irras dft; piano stool; surface; orientation ... See more keywords