Catalyst-Controlled Annulations of Strained Cyclic Allenes with π-Allylpalladium Complexes.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c03102
Abstract: Strained cyclic allenes are a class of in situ-generated fleeting intermediates that, despite being discovered more than 50 years ago, has received significantly less attention from the synthetic community compared to related strained intermediates. Examples… read more here.
Keywords: allenes allylpalladium; annulations strained; strained cyclic; catalyst controlled ... See more keywords
Access to Complex Scaffolds Through [2 + 2] Cycloadditions of Strained Cyclic Allenes.
Sign Up to like & getrecommendations! Published in 2024 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c03369
Abstract: We report the strain-induced [2 + 2] cycloadditions of cyclic allenes for the assembly of highly substituted cyclobutanes. By judicious choice of trapping agent, complex scaffolds bearing heteroatoms, fused rings, contiguous stereocenters, spirocycles, and quaternary… read more here.
Keywords: access complex; strained cyclic; complex scaffolds; cyclic allenes ... See more keywords