Early‐Stage Incorporation Strategy for Regioselective Labeling of Peptides using the 2‐Cyanobenzothiazole/1,2‐Aminothiol Bioorthogonal Click Reaction
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DOI: 10.1002/open.201700191
Abstract: Abstract Herein, we describe a synthetic strategy for the regioselective labeling of peptides by using a bioorthogonal click reaction between 2‐cyanobenzothiazole (CBT) and a 1,2‐aminothiol moiety. This methodology allows for the facile and site‐specific modification… read more here.
Keywords: click reaction; strategy regioselective; labeling peptides; reaction ... See more keywords
A Strategy for Regioselective B−H Functionalization of o-Carboranes via Base Metal Catalysis
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DOI: 10.1039/d3qo00621b
Abstract: Carboranes, a class of carbon-boron molecular clusters, own unique characteristics and are finding a variety of applications ranging from materials to medicine. In this connection, selective functionalization of o-carboranes has... read more here.
Keywords: via base; functionalization; carboranes via; functionalization carboranes ... See more keywords