Redox-Neutral Strategy for Sulfilimines Synthesis via S-Arylation of Sulfenamides.
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DOI: 10.1021/acs.orglett.3c01077
Abstract: In this investigation, an unprecedented transition-metal-free and redox-neutral synthesis of sulfilimines was realized through the S-arylation of readily obtainable sulfenamides employing diaryliodonium salts. The pivotal step encompassed the resonance between bivalent nitrogen-centered anions, engendered postdeprotonation… read more here.
Keywords: neutral strategy; synthesis; strategy sulfilimines; arylation ... See more keywords