Generation of Strong Basicity in Metal-Organic Frameworks: How Do Coordination Solvents Matter?
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.1c24299
Abstract: Solid strong bases with an ordered pore structure (OPS-SSBs) have attracted much attention because of their high catalytic activity and shape selectivity as heterogeneous catalysts in various reactions. Nevertheless, high temperatures are required to fabricate… read more here.
Keywords: coordination solvents; basicity; generation; metal ... See more keywords
An alkyl-substituted aluminium anion with strong basicity and nucleophilicity
Sign Up to like & getrecommendations! Published in 2019 at "Nature Chemistry"
DOI: 10.1038/s41557-019-0365-z
Abstract: Aluminium anions with an unoccupied orbital are generally considered as highly difficult synthetic targets, as aluminium is the most electropositive element in the p block. Stabilizing effects from two nitrogen substituents and/or the coordination of… read more here.
Keywords: anion; alkyl substituted; aluminium; strong basicity ... See more keywords