Articles with "strong electron" as a keyword



Ferrous metal-organic frameworks with strong electron-donating properties for persulfate activation to effectively degrade aqueous sulfamethoxazole.

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Published in 2020 at "Chemical engineering journal"

DOI: 10.1016/j.cej.2020.125044

Abstract: Three novel persulfate activators, Fe(II)-based metal-organic frameworks (MOFs) were synthesized for the degradation of sulfamethoxazole (SMX). The degradation experiment results showed that all the Fe(II)MOFs could effectively activate persulfate and degrade more than 97% SMX… read more here.

Keywords: donating properties; metal organic; strong electron; activation ... See more keywords
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Non-fullerene electron acceptors constructed by four strong electron-withdrawing end groups: Potential to improve the photoelectric performance of organic solar cells by theoretical investigations

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Published in 2020 at "Dyes and Pigments"

DOI: 10.1016/j.dyepig.2020.108542

Abstract: Abstract Recent advances in non-fullerene acceptors have enabled the power conversion efficiencies of organic solar cells (OSCs) to exceed 16%. Fused-ring electron acceptors (FREAs) are some of the most widely investigated non-fullerene acceptors. Classical FREAs,… read more here.

Keywords: electron withdrawing; non fullerene; strong electron; end groups ... See more keywords

Zero-Dimensional (Piperidinium)2MnBr4: Ring Puckering-Induced Isostructural Transition and Strong Electron-Phonon Coupling-Mediated Self-Trapped Exciton Emission.

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Published in 2022 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.2c01601

Abstract: We report on the synthesis, structure, and photophysical properties of a lead-free organic-inorganic hybrid halide, (Piperidinium)2MnBr4 (PipMBr). It crystallizes in a monoclinic P21/n structure, with isolated MnBr4 tetrahedra representing a zero-dimensional compound. It undergoes a… read more here.

Keywords: phonon coupling; piperidinium 2mnbr4; strong electron; emission ... See more keywords

Realizing Near-Unity Photoluminescence Efficiency in Antimony-Doped Indium-Based Halides Induced by Strong Electron-Phonon Coupling.

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Published in 2024 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.4c03666

Abstract: Exploring a zero-dimensional (0D) hybrid halide with a large Stokes shift and efficient broad-band emission is highly desirable due to its enormous potential for solid-state lighting (SSL) application. However, it is still challenging to develop… read more here.

Keywords: phonon coupling; electron phonon; indium based; strong electron ... See more keywords

Trap State Modulation via Strong Electron-Withdrawing Groups for Enhanced Vacuum Surface Insulation of All-Organic Polyimide.

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Published in 2025 at "ACS applied materials & interfaces"

DOI: 10.1021/acsami.5c10530

Abstract: Polyimide (PI), a high-performance polymer widely employed in aerospace applications due to its superior electrical insulation, processability, and long-term stability, faces operational challenges at vacuum-solid interfaces. Under extreme space conditions, vacuum flashover phenomena frequently occur… read more here.

Keywords: insulation; surface; strong electron; withdrawing groups ... See more keywords

Electrochemical on-surface synthesis of a strong electron-donating graphene nanoribbon catalyst

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Published in 2024 at "Nature Communications"

DOI: 10.1038/s41467-024-50086-6

Abstract: On-surface synthesis of edge-functionalized graphene nanoribbons (GNRs) has attracted much attention. However, producing such GNRs on a large scale through on-surface synthesis under ultra-high vacuum on thermally activated metal surfaces has been challenging. This is… read more here.

Keywords: surface synthesis; strong electron; electron donating; surface ... See more keywords
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Fermi blockade of the strong electron–phonon interaction in modelled optimally doped high temperature superconductors

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Published in 2021 at "Scientific Reports"

DOI: 10.1038/s41598-021-89059-w

Abstract: We study how manifestations of strong electron–phonon interaction depend on the carrier concentration by solving the two-dimensional Holstein model for the spin-polarized fermions using an approximation free bold-line diagrammatic Monte Carlo method. We show that… read more here.

Keywords: strong electron; electron phonon; phonon interaction;

Aggregation-induced emission fluorophores based on strong electron-acceptor 2,2'-(anthracene-9,10-diylidene) dimalononitrile for biological imaging in the NIR-II window.

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Published in 2021 at "Chemical communications"

DOI: 10.1039/d1cc00742d

Abstract: In this communication, three novel donor-acceptor-donor type second near-infrared AIE fluorophores based on strong electron-acceptor 2,2'-(anthracene-9,10-diylidene) dimalononitrile have been successfully developed for bioimaging, in which they exhibit good photostability and can be used in mouse… read more here.

Keywords: fluorophores based; electron acceptor; strong electron; acceptor anthracene ... See more keywords

Viologen linker as a strong electron transfer mediator in covalent organic framework to enhance electrocatalytic CO2 reduction

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Published in 2023 at "Materials Chemistry Frontiers"

DOI: 10.1039/d3qm00218g

Abstract: Covalent organic frameworks (COF) would be one class of promising candidates for the CO2 electroreduction reaction (CO2RR) due to their advantages of tunable structures, abundant active sites and strong CO2... read more here.

Keywords: linker strong; electron transfer; viologen linker; covalent ... See more keywords

Facile End-Capping Strategy with Strong Electron Withdrawing Groups for Enhancing Field-Effect Mobility

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Published in 2025 at "Journal of Materials Chemistry C"

DOI: 10.1039/d5tc00295h

Abstract: Optimizing energy levels and molecular packing is critical for the development of high-mobility polymer semiconductors. However, this is generally challenged by complicated molecular engineering and synthetic procedures. In this study,... read more here.

Keywords: mobility; capping strategy; facile end; strong electron ... See more keywords

Aspects of strong electron–phonon coupling in superconductivity of compressed metal hydrides MH6 (M = Mg, Ca, Sc, Y) with Im-3m structure

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Published in 2021 at "Journal of Applied Physics"

DOI: 10.1063/5.0062162

Abstract: Recently, YH6 was synthesized as a first compound from theoretically predicted stable compressed MH6 hydrides with bcc Im-3m crystal structures. Superconductivity of pressurized YH6 was confirmed with critical temperature (Tc) that is considerably lower than… read more here.

Keywords: electron phonon; phonon coupling; anti adiabatic; strong electron ... See more keywords