Strong influence of intramolecular Si...O proximity on reactivity: Systematic molecular structure, solvolysis, and mechanistic study of cyclic N-trimethylsilyl carboxamide derivatives
Sign Up to like & getrecommendations! Published in 2017 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2017.04.057
Abstract: A comparative alcoholysis study of N-silylated derivatives of simple heterocyclic carboxamides (lactams, imides, ureas) is presented. The second-order rate constant values span a range as wide as three orders of magnitude. On the basis of… read more here.
Keywords: strong influence; study; mechanistic study; reactivity ... See more keywords
Strong Influence of Ancillary Ligands Containing Benzothiazole or Benzimidazole Rings on Cytotoxicity and Photoactivation of Ru(II) Arene Complexes.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b02299
Abstract: A new family of neutral ruthenium(II) arene complexes of the type [Ru(η6-arene)X(κ2- O, N-L)] (η6-arene = p-cym, bz; X = Cl-, SCN-; HL1 = 2-(2'-hydroxyphenyl)benzimidazole, HL2 = 2-(2'-hydroxyphenyl)benzothiazole) has been synthesized and characterized. The cytotoxic… read more here.
Keywords: irradiation; strong influence; arene; photoactivation ... See more keywords
Strong influence of solar X-ray flares on low-frequency electromagnetic signals in middle latitudes
Sign Up to like & getrecommendations! Published in 2019 at "Annales Geophysicae"
DOI: 10.5194/angeo-37-843-2019
Abstract: Abstract. In this paper we analysed sudden phase anomalies (SPAs) of VLF–LF signals recorded at Graz (Austria), Birr (Ireland) and Moscow (Russia) stations during two strong solar flares in September 2017. The first X-class 9.3 flare occurred… read more here.
Keywords: solar ray; ray flares; ray; strong influence ... See more keywords