Articles with "strong metal" as a keyword



Photobreeding Method for Direct Construction and Continuous Tuning of Strong Metal–Support Interactions at Room Temperature

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Published in 2025 at "Advanced Science"

DOI: 10.1002/advs.202509904

Abstract: The construction of strong metal–support interactions (SMSI) is an effective strategy to enhance and control heterogeneous catalysts. However, conventional methods require pre‐synthesized metal‐loaded catalysts, followed by SMSI formation via high‐temperature treatment under oxidative/reductive atmospheres, adsorbate‐mediated… read more here.

Keywords: temperature; support interactions; metal; strong metal ... See more keywords

The Synergistic Effect of Pyrrolic‐N and Pyridinic‐N with Pt Under Strong Metal‐Support Interaction to Achieve High‐Performance Alkaline Hydrogen Evolution

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Published in 2022 at "Advanced Energy Materials"

DOI: 10.1002/aenm.202200110

Abstract: Developing high‐performance Pt‐based catalysts with strong metal‐support interaction (SMSI) is significant for hydrogen production by water electrolysis working at high current density conditions, but still challenging. Herein, Pt/X‐NCNT (X = 4, 8, 12, 16) with… read more here.

Keywords: metal support; strong metal; synergistic effect; support interaction ... See more keywords

Reversible Strong Metal‐Support Interactions in Co/TiO 2 Catalysts Driven by CO 2

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Published in 2025 at "ChemCatChem"

DOI: 10.1002/cctc.202501392

Abstract: Strong metal–support interactions can significantly influence catalytic performance. On titania supports, these interactions often involve the formation of a substoichiometric TiOX overlayer during high‐temperature reduction, which can be reversed by treatments under dioxygen. Under CO2… read more here.

Keywords: metal support; strong metal; support interactions; overlayer ... See more keywords

Strong Metal-Support Interactions in Heterogeneous Oxygen Electrocatalysis.

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Published in 2024 at "Small"

DOI: 10.1002/smll.202407167

Abstract: Molecular oxygen redox electrocatalysis involves oxygen reduction and evolution as core reactions in various energy conversion and environmental technology fields. Strong metal-support interactions (SMSIs) based nanomaterials are regarded as desirable and state-of-the-art heterogeneous electrocatalysts due… read more here.

Keywords: oxygen; support interactions; electrocatalysis; strong metal ... See more keywords
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Sintering-resistant Au/iron oxide-hydroxyapatite nanocatalysts achieved by tuning strong metal-support interactions

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Published in 2021 at "Catalysis Today"

DOI: 10.1016/j.cattod.2021.01.012

Abstract: Abstract Supported gold nanocatalysts have been treated as extraordinarily effective catalysts in heterogeneous catalysis field. However, their poor thermodynamic stability in reactions at elevated temperature remains to be resolved for practical applications. The strong metal-support… read more here.

Keywords: sintering resistant; metal support; support; strong metal ... See more keywords

Ru/Mn Ce1O catalysts with enhanced oxygen mobility and strong metal-support interaction: Exceptional performances in 5-hydroxymethylfurfural base-free aerobic oxidation

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Published in 2018 at "Journal of Catalysis"

DOI: 10.1016/j.jcat.2018.09.034

Abstract: Abstract Mn-Ce mixed oxides-supported Ru nanoparticles (Ru/MnXCe1OY) with enhanced oxygen mobility and strong metal-support interaction were prepared and applied to the aerobic oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA) without addition of any base… read more here.

Keywords: oxygen; metal support; support; strong metal ... See more keywords

Electronegativity Enhanced Strong Metal-Support Interaction in Ru@F-Ni3N for Enhanced Alkaline Hydrogen Evolution.

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Published in 2022 at "ACS applied materials & interfaces"

DOI: 10.1021/acsami.2c09507

Abstract: Precious metals (Pt, Ir, Ru, and so on) and related compounds usually demonstrate superb catalytic activity for electrochemical hydrogen production. However, scarcity and stability are still challenges for hydrogen evolution reaction, even for single-atomic-site electrocatalysts.… read more here.

Keywords: metal support; strong metal; hydrogen; support interaction ... See more keywords
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In Situ Strong Metal–Support Interaction (SMSI) Affects Catalytic Alcohol Conversion

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Published in 2021 at "ACS Catalysis"

DOI: 10.1021/acscatal.0c05324

Abstract: Strong metal–support interactions (SMSIs) and catalyst deactivation have been heavily researched for decades by the catalysis community. The promotion of SMSIs in supported metal oxides is commonly... read more here.

Keywords: support interaction; strong metal; situ strong; metal support ... See more keywords

Experimental and Theoretical Understanding of Nitrogen-Doping-Induced Strong Metal–Support Interactions in Pd/TiO2 Catalysts for Nitrobenzene Hydrogenation

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Published in 2017 at "ACS Catalysis"

DOI: 10.1021/acscatal.6b02963

Abstract: By doping the TiO2 support with nitrogen, strong metal–support interactions (SMSI) in Pd/TiO2 catalysts can be tailored to obtain high-performance supported Pd nanoparticles (NPs) in nitrobenzene (NB) hydrogenation catalysis. According to the comparative studies by… read more here.

Keywords: hydrogenation; metal support; tio2 catalysts; support interactions ... See more keywords

Subnanometric Gold Clusters on CeO2 with Maximized Strong Metal–Support Interactions for Aerobic Oxidation of Carbon–Hydrogen Bonds

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Published in 2018 at "ACS Sustainable Chemistry & Engineering"

DOI: 10.1021/acssuschemeng.8b00202

Abstract: We report the synthesis of subnanometric Au clusters with average diameters at 1.2 nm on a low-crystallinity CeO2 support (sub-Au/LC-CeO2), which exhibit high activities and selectivities in the aerobic oxidation of C–H bonds on a… read more here.

Keywords: metal support; maximized strong; aerobic oxidation; support interactions ... See more keywords

Renaissance of Strong Metal-Support Interactions.

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Published in 2024 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.3c09102

Abstract: Strong metal-support interactions (SMSIs) have emerged as a significant and cutting-edge area of research in heterogeneous catalysis. They play crucial roles in modifying the chemisorption properties, interfacial structure, and electronic characteristics of supported metals, thereby… read more here.

Keywords: renaissance strong; support interactions; strong metal; metal ... See more keywords