The Synergistic Effect of Pyrrolic‐N and Pyridinic‐N with Pt Under Strong Metal‐Support Interaction to Achieve High‐Performance Alkaline Hydrogen Evolution
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Energy Materials"
DOI: 10.1002/aenm.202200110
Abstract: Developing high‐performance Pt‐based catalysts with strong metal‐support interaction (SMSI) is significant for hydrogen production by water electrolysis working at high current density conditions, but still challenging. Herein, Pt/X‐NCNT (X = 4, 8, 12, 16) with… read more here.
Keywords: metal support; strong metal; synergistic effect; support interaction ... See more keywords
Sintering-resistant Au/iron oxide-hydroxyapatite nanocatalysts achieved by tuning strong metal-support interactions
Sign Up to like & getrecommendations! Published in 2021 at "Catalysis Today"
DOI: 10.1016/j.cattod.2021.01.012
Abstract: Abstract Supported gold nanocatalysts have been treated as extraordinarily effective catalysts in heterogeneous catalysis field. However, their poor thermodynamic stability in reactions at elevated temperature remains to be resolved for practical applications. The strong metal-support… read more here.
Keywords: sintering resistant; metal support; support; strong metal ... See more keywords
Ru/Mn Ce1O catalysts with enhanced oxygen mobility and strong metal-support interaction: Exceptional performances in 5-hydroxymethylfurfural base-free aerobic oxidation
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2018.09.034
Abstract: Abstract Mn-Ce mixed oxides-supported Ru nanoparticles (Ru/MnXCe1OY) with enhanced oxygen mobility and strong metal-support interaction were prepared and applied to the aerobic oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA) without addition of any base… read more here.
Keywords: oxygen; metal support; support; strong metal ... See more keywords
Electronegativity Enhanced Strong Metal-Support Interaction in Ru@F-Ni3N for Enhanced Alkaline Hydrogen Evolution.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c09507
Abstract: Precious metals (Pt, Ir, Ru, and so on) and related compounds usually demonstrate superb catalytic activity for electrochemical hydrogen production. However, scarcity and stability are still challenges for hydrogen evolution reaction, even for single-atomic-site electrocatalysts.… read more here.
Keywords: metal support; strong metal; hydrogen; support interaction ... See more keywords
In Situ Strong Metal–Support Interaction (SMSI) Affects Catalytic Alcohol Conversion
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DOI: 10.1021/acscatal.0c05324
Abstract: Strong metal–support interactions (SMSIs) and catalyst deactivation have been heavily researched for decades by the catalysis community. The promotion of SMSIs in supported metal oxides is commonly... read more here.
Keywords: support interaction; strong metal; situ strong; metal support ... See more keywords
Experimental and Theoretical Understanding of Nitrogen-Doping-Induced Strong Metal–Support Interactions in Pd/TiO2 Catalysts for Nitrobenzene Hydrogenation
Sign Up to like & getrecommendations! Published in 2017 at "ACS Catalysis"
DOI: 10.1021/acscatal.6b02963
Abstract: By doping the TiO2 support with nitrogen, strong metal–support interactions (SMSI) in Pd/TiO2 catalysts can be tailored to obtain high-performance supported Pd nanoparticles (NPs) in nitrobenzene (NB) hydrogenation catalysis. According to the comparative studies by… read more here.
Keywords: hydrogenation; metal support; tio2 catalysts; support interactions ... See more keywords
Subnanometric Gold Clusters on CeO2 with Maximized Strong Metal–Support Interactions for Aerobic Oxidation of Carbon–Hydrogen Bonds
Sign Up to like & getrecommendations! Published in 2018 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.8b00202
Abstract: We report the synthesis of subnanometric Au clusters with average diameters at 1.2 nm on a low-crystallinity CeO2 support (sub-Au/LC-CeO2), which exhibit high activities and selectivities in the aerobic oxidation of C–H bonds on a… read more here.
Keywords: metal support; maximized strong; aerobic oxidation; support interactions ... See more keywords
Strong metal-support interactions: An extra layer of complexity.
Sign Up to like & getrecommendations! Published in 2017 at "Nature chemistry"
DOI: 10.1038/nchem.2724
Abstract: Strong interactions between oxide supports and catalytic metal particles can lead to inhibitive oxide layers forming over the active metal catalyst. Now, adsorbate-induced metal–support interactions have been shown to lead to a porous overlayer in… read more here.
Keywords: metal support; metal; interactions extra; support interactions ... See more keywords
Experimental and computational study on roles of WOx promoting strong metal support promoter interaction in Pt catalysts during glycerol hydrogenolysis
Sign Up to like & getrecommendations! Published in 2021 at "Scientific Reports"
DOI: 10.1038/s41598-020-79764-3
Abstract: Biodiesel is of high interest due to increased demand for energy with the concern regarding more sustainable production processes. However, an inevitable by-product is glycerol. Hence, the conversion of this by-product to higher-value chemicals, especially… read more here.
Keywords: promoter; metal support; glycerol hydrogenolysis; interaction ... See more keywords
Ultralong-lifetime Ti/RuO2-IrO2@Pt anodes with a strong metal-support interaction for efficient electrochemical mineralization of perfluorooctanoic acid.
Sign Up to like & getrecommendations! Published in 2022 at "Nanoscale"
DOI: 10.1039/d1nr08098a
Abstract: Electrocatalytic oxidation is regarded as an effective technique for decomposing refractory organic compounds like perfluorooctanoic acid (PFOA). However, achieving highly efficient and long-life electrodes is still a great challenge. Herein, Ti/RuO2-IrO2@Pt anodes consisting of Pt4+… read more here.
Keywords: strong metal; iro2 anodes; perfluorooctanoic acid; ruo2 iro2 ... See more keywords
Atomic origins of the strong metal–support interaction in silica supported catalysts
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Science"
DOI: 10.1039/d1sc03480d
Abstract: Silica supported metal catalysts are most widely used in the modern chemical industry because of the high stability and tunable reactivity. The strong metal–support interaction (SMSI), which has been widely observed in metal oxide supported… read more here.
Keywords: metal support; silica; sio2; supported catalysts ... See more keywords