Articles with "strong trans" as a keyword



Photo by marivlassi from unsplash

Very strong trans effect in ruthenacyclic carbamoyl complexes leads to ligand redistribution in phosphine derivatives

Sign Up to like & get
recommendations!
Published in 2019 at "Journal of Organometallic Chemistry"

DOI: 10.1016/j.jorganchem.2019.02.022

Abstract: Abstract The ruthenacyclic carbamoyl complexes [Ru (2-NHC(O)C5H4N) (CO)2(X) (NCMe)] (X = Cl, Br) (1) and [Ru (2-NHC(O)C5H4N) (CO)2 (2-S-Py)] (2) undergo substitution reactions with organophosphines to afford derivatives which are prone to a redistribution of the phosphine… read more here.

Keywords: redistribution; carbamoyl complexes; strong trans; trans effect ... See more keywords