Rapid Access to the Structural Core of Aflavinines via Stereoselective Tandem Intramolecular Diels-Alder Cycloaddition Controlled by the Allylic 1,3-Strain.
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DOI: 10.1021/acs.orglett.9b02457
Abstract: An expedient route to access the functionalized structural core of aflavinines has been developed starting from three readily available fragments over 12 steps in 29.1% overall yield without using any transition metal catalysis. The key… read more here.
Keywords: tandem intramolecular; diels alder; core aflavinines; structural core ... See more keywords