Synthesis and Structure of Bismuth-Nitrogen Cage Compounds and Heterocubanes: [Cl-Bi(μ3-N-TMP)]4: A Dimer of a 1,3-Dichloro-cyclo-dibismadiazane.
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DOI: 10.1021/acs.inorgchem.9b03221
Abstract: The reaction of TMP-NH2 [TMP = m,m-(CF3)2-C6H3] with 2 equiv of n-BuLi led to the in situ formation of Li2[N-TMP], which, after the addition of BiCl3, formed a [Cl-Bi(μ3-N-TMP)]4-type heterocubane in up to 30% yield.… read more here.
Keywords: tmp; structure bismuth; cage compounds; synthesis structure ... See more keywords
Enhanced thermoelectricity by controlled local structure in bismuth-chalcogenides
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DOI: 10.1063/1.5087096
Abstract: Spectroscopic techniques, including photoelectron spectroscopy, diffuse reflectance, and x-ray absorption, are used to investigate the electronic structure and the local structure of LaOBiS 2 − xSe x thermoelectric material. It is found that Se substitution… read more here.
Keywords: thermoelectricity controlled; structure bismuth; controlled local; local structure ... See more keywords