The structure of a pentachromium(II) extended metal atom chain at 3 K: Cotton's conjecture proven.
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DOI: 10.1039/d2dt03103e
Abstract: We provide definitive experimental proof that the archetypal string-like compound [Cr5(tpda)4(NCS)2] has alternating long and short Cr-Cr separations in the solid state, as conjectured by F. A. Cotton, rather than essentially equally spaced Cr atoms,… read more here.
Keywords: structure pentachromium; pentachromium extended; atom chain; cotton ... See more keywords