Diversity of Structures and Bonding in Alkali Metal Ureaphosphanes
Sign Up to like & getrecommendations! Published in 2024 at "Helvetica Chimica Acta"
DOI: 10.1002/hlca.202400077
Abstract: While organoelement compounds of lithium, sodium and potassium have been much studied for decades and consequently have found forests of applications, those of the heavier alkali metals, rubidium and caesium would barely manage to fill… read more here.
Keywords: diversity structures; alkali metal; structures bonding; caesium ... See more keywords
Geometries, electronic structures, and bonding properties of endohedral Group‐14 Zintl clusters TM@E10 (TM = Fe, Co, Ni; E = Ge, Sn, Pb)
Sign Up to like & getrecommendations! Published in 2022 at "Journal of Computational Chemistry"
DOI: 10.1002/jcc.26838
Abstract: The geometries, electronic structures, and bonding properties of the title endohedral Zintl clusters have been studied by using ab initio calculations. [Fe@Ge10]4− and [Co@Ge10]3− have D5h‐symmetric pentagonal prismatic structure and [Fe@Sn10]4− adopts the C2v‐symmetric structure… read more here.
Keywords: electronic structures; structures bonding; geometries electronic; bonding properties ... See more keywords
Diarylpnictogenyldialkylalanes─Synthesis, Structures, Bonding Analysis, and CO2 Capture.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03494
Abstract: Several new diphenylamino- and diphenylphosphanyldialkylalanes are reported, which were characterized in solution and in the solid state, assisted by in-depth bonding analysis within the DFT framework. In the case of bulky alkyl substituents on the… read more here.
Keywords: diarylpnictogenyldialkylalanes synthesis; structures bonding; analysis; synthesis structures ... See more keywords
Structures, Bonding and Sensor Properties of Some Alkaline o-Phthalatocuprates
Sign Up to like & getrecommendations! Published in 2021 at "Materials"
DOI: 10.3390/ma14195548
Abstract: Comprehensive study of the structure and bonding of disodium, dipotassium and diammonium di-o-phthalatocuprates(II) dihydrates has been undertaken. The crystal structure of ammonium o-phthalatocuprate has been determined. The identity of structures of phthalatocuprate chains in potassium… read more here.
Keywords: sensor properties; alkaline phthalatocuprates; bonding sensor; properties alkaline ... See more keywords