Crystal structures of 3/4-pyridyl-based thiosemicarbazones and related Cu and Ni coordination compounds.
Sign Up to like & getrecommendations! Published in 2022 at "Acta crystallographica. Section C, Structural chemistry"
DOI: 10.1107/s205322962101319x
Abstract: In this investigation, the crystal structures of the thio-ligands 3-formylpyridine 4-phenylthiosemicarbazone (C13H12N4S, 1) and 4-benzoylpyridine 4-ethylthiosemicarbazone (C15H16N4S, 2), and of two new coordination compounds, chlorido(3-formylpyridine 4-phenylthiosemicarbazone-κS)bis(triphenylphosphane-κP)copper(I) acetonitrile monosolvate, [CuCl(C13H12N4S)(C18H15P)2]·CH3CN, 3, and bis(3-formylpyridine 4-ethylthiosemicarbazonato-κ2N1,S)nickel(II), [Ni(C9H11N4S)2], 4,… read more here.
Keywords: coordination compounds; structures pyridyl; pyridyl based; based thiosemicarbazones ... See more keywords
Anion influences on the structures of pyridyl-iminosulfonate copper(II) complexes and their reactivity in Chan–Lam couplings
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DOI: 10.1139/cjc-2020-0003
Abstract: Reaction of pyridylcarbaldehyde with taurine or orthanilic acid in the presence of copper salts provided copper complexes (PyC(H)N-CxHy-SO3)CuX with X = chloride, nitrate, acetate, or triflate and ... read more here.
Keywords: copper complexes; pyridyl iminosulfonate; copper; anion influences ... See more keywords