Reactivity studies of an imine-functionalised phosphaalkene; unusual electrostatic and supramolecular stabilisation of a σ2λ3-phosphorus motif via hydrogen bonding.
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DOI: 10.1039/c8dt01607k
Abstract: A P[double bond, length as m-dash]C heavy-alkene analogue that is unreactive towards the addition of strong acids on its double-bond is presented; instead, a strategically located imine nitrogen on the periphery forms protonated adducts displaying… read more here.
Keywords: studies imine; hydrogen; stabilisation; reactivity studies ... See more keywords