Kinetico‐Mechanistic Studies of Cu(II)‐Mediated Cyclization of Imines via C–H Bond Activations§
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DOI: 10.1002/ejic.202400564
Abstract: Herein, we focus on the kinetico‐mechanistic studies of a carboxylate and Cu(II)‐assisted synthesis of imidazo[1,5‐a]pyridines encompassing C(sp3)–H amination and cyclization of imines coupled with C(sp2)–H cyanation using time‐resolved UV‐Vis reaction monitoring and ex‐situ analyses. Thus,… read more here.
Keywords: studies mediated; cyclization imines; bond; mechanistic studies ... See more keywords
DFT Studies on Ni-Mediated C–F Cleavage for the Synthesis of Cyclopentadiene Derivatives
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DOI: 10.3389/fchem.2018.00319
Abstract: Density functional theory calculations have been performed to study the detailed mechanism of Ni-mediated [3+2] cycloaddition of 2-trifluoromethyl-1-alkenes with alkynes via cleavage of two C-F bonds. It was found that the reaction pathway involves oxidative… read more here.
Keywords: studies mediated; dft studies; mediated cleavage; cleavage ... See more keywords