Studies Relevant to the Functional Model of Mo-Cu CODH: In Situ Reactions of Cu(I)-L Complexes with Mo(VI) and Synthesis of Stable Structurally Characterized Heterotetranuclear MoVI2CuI2 Complex
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DOI: 10.3390/molecules28083644
Abstract: In this study, we report the synthesis, characterization, and reactions of Cu(I) complexes of the general form Cu(L)(LigH2) (LigH2 = xanthene-based heterodinucleating ligand (E)-3-(((5-(bis(pyridin-2-ylmethyl)amino)-2,7-di-tert-butyl-9,9-dimethyl-9H-xanthen-4-yl)imino)methyl)benzene-1,2-diol); L = PMe3, PPh3, CN(2,6-Me2C6H3)). New complexes [Cu(PMe3)(LigH2)] and [CuCN(2,6-Me2C6H3)(LigH2)] were… read more here.
Keywords: ligh2; spectroscopy; studies relevant; synthesis ... See more keywords