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Comprehensive Experimental and Computational Study of η6-Arene Ruthenium(II) and Osmium(II) Complexes Supported by Sulfur Analogues of the β-Diketiminate Ligand

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Published in 2018 at "Organometallics"

DOI: 10.1021/acs.organomet.8b00111

Abstract: In comparison to β-diketiminates, a highly exploited class of N,N-chelating ligands, the corresponding β-thioketoiminates, monothio-substituted analogues, have received only minor attention. β-Thioketoiminates are straightforwardly prepared through treatment of an appropriate β-ketoiminate with Lawesson’s reagent. Employing… read more here.

Keywords: complexes supported; comprehensive experimental; computational study; study arene ... See more keywords