Metal oxide sub-nanoclusters decorated Ni catalyst for selective hydrogenation of adiponitrile to hexamethylenediamine
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DOI: 10.1016/j.jcat.2019.10.024
Abstract: Abstract Nickel based catalysts were decorated by metal oxide (MOx = CeO2, La2O3 or MgO) and used for the selective hydrogenation of adiponitrile to hexamethylenediamine. Additional MOx sub-nanoclusters were dispersed on surface to manipulate the electron and… read more here.
Keywords: hydrogenation adiponitrile; selective hydrogenation; metal oxide; adiponitrile hexamethylenediamine ... See more keywords
Tetrahexahedral binary transition metal compound sub-nanoclusters
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DOI: 10.1063/5.0190997
Abstract: We explore new transition metal (TM) compound sub-nanoclusters, TM8X6 (TM = Mn, Fe, Co and X = P, B, As), using density functional theory. Their optimized geometric structures show the same polyhedral structure (tetrahexahedron) independent… read more here.
Keywords: compound sub; metal compound; transition metal; sub nanoclusters ... See more keywords