Substituents make a difference: 6,6″-modified terpyridine complexes with helix configuration and enhanced emission.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d2dt04006a
Abstract: A series of complexes L22-M (L2: 6,6″-bis(4-methoxyphenyl)-4'-phenyl-2,2':6',2″-terpyridine, M: Mn2+, Fe2+, Co2+, Ni2+, Cu2+, Zn2+) were synthesized by coordinating p-methoxyphenyl 6,6″-substituted terpyridine ligand with first-row transition metal ions and characterized by NMR, ESI-MS, and X-ray single… read more here.
Keywords: terpyridine; emission; geometry; substituents make ... See more keywords