Articles with "substitute axial" as a keyword



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A synthetic tactic to substitute axial ligands in sterically demanding Ru(II)porphyrinates.

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Published in 2022 at "Dalton transactions"

DOI: 10.1039/d2dt01095j

Abstract: We report a synthetic strategy that allows for the preparation of sterically encumbered heteroleptic Ru(II)porphyrinates with the desired configuration of stable/inert and weak/labile axial ligands to direct reactions between substrates to exclusively occur at the… read more here.

Keywords: tactic substitute; substitute axial; axial ligands; sterically demanding ... See more keywords