Copper(I)‐Catalyzed CuAIAC/Allylation Cascade: Modular Synthesis of Fully Substituted Allyl N,N′ ‐Bicyclic Pyrazolidinones
Sign Up to like & getrecommendations! Published in 2025 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.70272
Abstract: A copper(I)‐catalyzed CuAIAC/allylation cascade reaction exploiting alkynes, azomethine imines, and allyl bromides has been developed for providing rapid access to fully substituted allyl N,N ′‐bicyclic pyrazolidinones, involving the formation of C(sp 2 )–C(sp 3 )… read more here.
Keywords: catalyzed cuaiac; cuaiac allylation; substituted allyl; fully substituted ... See more keywords
Enantioselective Construction of Aza-bicyclo[3.2.1]octane Skeletons via Substituted π-Allyl Palladium Dipoles Originated from Neutral η3-Propargyl Palladium Species.
Sign Up to like & getrecommendations! Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.5c10764
Abstract: A catalytic strategy for insitu generation of substituted π-allyl palladium dipoles from neutral η3 -propargyl palladium complexes has been disclosed, enabling the construction of enantiomerically enriched aza-bicyclo[3.2.1]octane frameworks through cascade cyclization reactions based on neutral… read more here.
Keywords: palladium dipoles; allyl palladium; substituted allyl; propargyl palladium ... See more keywords
Pd-catalyzed enantioselective cyclopropanation of nitriles with mono substituted allyl carbonates enabled by the bulky N-heterocyclic carbene ligand.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc01960j
Abstract: A highly efficient catalyst for Pd-catalyzed cyclopropanation was developed using a bulkier N-heterocyclic carbene ligand, with which the nitriles reacted with mono substituted allyl reagents to afford cyclopropanes in high yields with high cyclopropanation/allylation and… read more here.
Keywords: cyclopropanation; mono substituted; carbene ligand; substituted allyl ... See more keywords
Oxidative coupling of N-nitrosoanilines with substituted allyl alcohols under rhodium (III) catalysis
Sign Up to like & getrecommendations! Published in 2024 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2024.1506493
Abstract: Rhodium(III) catalysis has been used for C-H activation of N-nitrosoanilines with substituted allyl alcohols. This method provides an efficient synthesis of the functional N-nitroso ortho β-aryl aldehydes and ketones with low catalyst loading, high functional… read more here.
Keywords: iii catalysis; allyl alcohols; substituted allyl; nitrosoanilines substituted ... See more keywords