Synthesis of symmetrically and unsymmetrically substituted S,S-dialkyl phosphonodithioates
Sign Up to like & getrecommendations! Published in 2017 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2017.09.065
Abstract: Abstract Herein, we report the synthesis of a range of S,S -dialkyl phosphonodithioates. Symmetrically substituted analogues were readily prepared from the corresponding phosphonic dichlorides in good to moderate yields, while unsymmetrically substituted variants were obtained… read more here.
Keywords: symmetrically unsymmetrically; synthesis symmetrically; substituted dialkyl; dialkyl phosphonodithioates ... See more keywords
Intramolecular Cyclizations of Vinyl-Substituted N,N-Dialkyl Arylamines Enabled by Borane-Assisted Hydride Transfer
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DOI: 10.1021/acscatal.8b04485
Abstract: Catalytic amounts of B(C6F5)3 have been found to be able to promote the intramolecular cyclization of vinyl-substituted N,N-dialkyl arylamines to afford nitrogen-containing heterocycles. Our mechanistic studies indicate the reaction is initiated by abstraction of an… read more here.
Keywords: hydride; substituted dialkyl; dialkyl arylamines; intramolecular cyclizations ... See more keywords
Synthesis, characterization and study of electrochemical applicability of novel asymmetrically substituted 1,3-dialkyl-1,2,3-benzotriazolium salts for supercapacitor fabrication
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DOI: 10.1039/d3ra01958f
Abstract: Here we report the successful synthesis, fabrication, and testing of novel asymmetrically substituted 1,3-dialkyl-1,2,3-benzotriazolium-based ionic liquids. Their applicability in energy storage is tested as gel polymer electrolytes (ILGPE) immobilized in poly(vinylidene fluoride-co-hexa-fluoropropylene) (PVDF-HFP) copolymer as… read more here.
Keywords: dialkyl benzotriazolium; benzotriazolium salts; spectroscopy; benzotriazolium ... See more keywords