Synthesis and Unusual Reactivity of Acyl-Substituted 1,4-Disilacyclohexa-2,5-dienes
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DOI: 10.1021/acs.organomet.2c00475
Abstract: In continuation of our recent studies on group 14 rings with exocyclic silicon–carbon double bonds, we report here on the synthesis and reactivity of previously unknown acyl-substituted 1,4-disilacyclohexa-2,5-dienes. 1,1,4,4-Tetrakistrimethylsilyl-1,4-disilacyclohexa-2,5-diene 1 cleanly afforded the silyl anion… read more here.
Keywords: synthesis unusual; acyl substituted; unusual reactivity; substituted disilacyclohexa ... See more keywords