Catalyst-Directed Guidance of Sulfur-Substituted Enediolates to Stereoselective Carbon-Carbon Bond Formation with Aldehydes.
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DOI: 10.1021/jacs.7b12949
Abstract: A highly chemo-, regio-, and stereoselective glycolate aldol reaction of sulfur-substituted enediolates with aldehydes was developed by employing a l-cyclohexylglycine-derived chiral iminophosphorane as a catalyst. The key for establishing this protocol is the distinct ability… read more here.
Keywords: carbon; carbon bond; substituted enediolates; carbon carbon ... See more keywords