Synthesis of mono/dinuclear rhenium(i) tricarbonyl substituted with 4-mercaptopyridine related ligands: spectral and theoretical evidence of thiolate/thione interconversion
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DOI: 10.1039/d0nj02328k
Abstract: The synthesis, characterization and spectroscopic and theoretical studies of new κ1-S monometallic Re-spy (1)/Re-thiopy (2) and κ1-N-bimetallic Re2-dps (3)/Re2-dpds (4) complexes substituted with 4-mercaptopyridine derivatives are reported. The obtainment of either monosulfide bridge-complex (3) or… read more here.
Keywords: substituted mercaptopyridine; synthesis mono; rhenium; synthesis ... See more keywords