Ylide-Substituted Phosphines: A Platform of Strong Donor Ligands for Gold Catalysis and Palladium-Catalyzed Coupling Reactions.
Sign Up to like & getrecommendations! Published in 2022 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.1c00797
Abstract: ConspectusThe development of homogeneous catalysts is strongly connected to the design of new, sophisticated ligands, which resolve limitations of a given reaction protocol by manipulating the electronic properties of the metal and its spatial environment.… read more here.
Keywords: substituted phosphines; coupling reactions; catalysis; donor ... See more keywords
Synthesis and Characterization of Polychlorinated Trityl Radical Substituted Phosphines.
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DOI: 10.1021/acs.orglett.4c04714
Abstract: We synthesized a series of polychlorinated trityl radical substituted phenylphosphines. Through UV-vis photoluminescence (PL) spectroscopy and cyclic voltammetry, we explored the influence of the chemical modifications (oxidation/reduction, coordination, and methylation) of the phosphorus center(s) on… read more here.
Keywords: trityl radical; radical substituted; substituted phosphines; synthesis characterization ... See more keywords